@Article{DammCoCaTrBaCo:2019:NoMeMi,
author = "Damm, D. D. and Contin, A. and Cardoso, L. D. R. and
Trava-Airoldi, Vladimir Jesus and Barquete, D. M. and Corat,
Evaldo Jos{\'e}",
affiliation = "{Universidade Federal de S{\~a}o Paulo (UNIFESP)} and
{Universidade Federal de Goi{\'a}s (UFG)} and {Instituto Nacional
de Pesquisas Espaciais (INPE)} and {Instituto Nacional de
Pesquisas Espaciais (INPE)} and {Universidade Estadual de Santa
Cruz} and {Instituto Nacional de Pesquisas Espaciais (INPE)}",
title = "A novel method to mitigate residual stress in CVD diamond
\film on steelsubstrates with a single intermediate layer",
journal = "Surface and Coatings Technology",
year = "2019",
volume = "357",
pages = "93--102",
keywords = "CVD diamond, Steel substrate, Vanadium carbide, Diffusional
barrier.",
abstract = "Direct deposition of CVD diamond on steel produces useless diamond
film which delaminates on cooling from deposition temperature
[19]. The majority of current research efforts focus on single and
multiple intermediate layers for CVD diamond deposition on steel
substrate. There are many excellent diffusional barriers to
transition metals migration from bulk to substrate surface to form
graphitic sp2 bonds. However, there is no practical solution to
the thermal expansion coefficient (TEC) mismatch between diamond
and steels. In this work we use a vanadium carbide thermodiffused
coating as the intermediate layer between diamond and AISI O1
steel substrate. It acts as a diffusional barrier and mitigates
diamond residual stress after cooling from CVD temperature.
Increasing vanadium carbide layer thickness creates a transition
zone that attenuates diamond residual stress. Up to now, the
vanadium carbide is the only single layer barrier able to inhibit
graphitic phase formation and mitigate residual stress in diamond
films to the level of 0.54 GPa.",
doi = "10.1016/j.surfcoat.2018.09.067",
url = "http://dx.doi.org/10.1016/j.surfcoat.2018.09.067",
issn = "0257-8972",
language = "en",
targetfile = "damm_novel.pdf",
urlaccessdate = "27 abr. 2024"
}